The Vampire Diaries (2009–2017)
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Yes, seasons 1-5 are available to own on DVD and Blu-ray while season 6 is only available for pre-order.
The Complete First Season was released in both DVD & Blu-ray formats on August 31st, 2010.
The Complete Second Season was released in both DVD & Blu-ray formats on August 30th, 2011.
The Complete Third Season was released in both DVD & Blu-ray formats on September 11th, 2012.
The Complete Fourth Season was released in both DVD & Blu-ray formats on September 3rd, 2013.
The Complete Fifth Season was released in both DVD & Blu-ray formats on September 9th, 2014.
The Complete Sixth Season will be released in both DVD and Blu-ray formats on September 1st, 2015.
Seasons 1-6 can be digitally downloaded from iTunes and Amazon. Edit
A The Vampire Diaries soundtrack including scene descriptions can be found on TuneFind.
Chris Mollere, the music supervisor tweets a complete song list after each episode airs in the US West Coast (It currently airs Thursdays @8PM ET). Follow him on twitter.
For music lists with scene descriptions, go here. You can also find the soundtracks in each episode on The Vampire Diaries Wikia. Edit
Season One: Damon Salvatore(no humanty), John Gilbert, and the old Vampires of 19th century Mystic Falls
Season Two: Katherine Pierce and Klaus Mikaelson
Season Three: Katherine Pierce, Klaus Mikaelson, Michael Mikaelson, Esther Mikaelson, and Alaric Saltzman(Under Esthers spell)
Season Four: Katherine Pierce, Klaus Mikaelson, the Hunters, and Silas
Season Five: Katherine Pierce, The scientists of Augustine, Silas, and the Travelers(led by Markos)
Season Six: Kai Parker, Caroline Forbes(no humanity), and the Heretics
Season Seven: The Heretics(partially), Julian, and Rayna Cruz
Season Eight: The Sirens(led by Arcadius), Kai Parker, Damon Salvatore(no humanity), and Katherine Pierce Edit